Segmental Orientation in Uniaxially Deformed Polymer Networks and Application to Orientation-Induced Crystallization. Volume 35, Number 11, May 21, 2002, pp 4493−4509.
نویسندگان
چکیده
منابع مشابه
Role of Structural Heterogeneities on Segmental Orientation in Deformed Chains: Application to Alternating Copolymers
Effects of intrinsic structural and conformational properties on segmental orientation in uniaxially deformed copolymers are considered. Depedence of segmental orientation on equilibrium values of bond angles, torsional states, and probability distribution of rotameric states is studied. Calculations are carried out for chains with independent as well as pairwise interdependent rotameric states...
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In order to understand orientation-induced crystallization of polymers, we introduced an intermolecular interaction between polymer chains based on quantum mechanics. We therefore considered a pair of perfectly extended chains where the intermolecular interaction is assumed to be based on the hydrogen interaction with a single chain. When two protons of each extended chain become closer togethe...
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ژورنال
عنوان ژورنال: Macromolecules
سال: 2002
ISSN: 0024-9297,1520-5835
DOI: 10.1021/ma020866k